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Quantum Theory

Electrogenerated Chemiluminescence: Protocols and by Saima Parveen, Muhammad Sohail Aslam, Lianzhe Hu, Guobao Xu

By Saima Parveen, Muhammad Sohail Aslam, Lianzhe Hu, Guobao Xu

This e-book basically specializes in the basics of and new advancements in electrochemiluminescence (ECL), providing fine quality content material and explicitly aiming to summarize and disseminate the present cutting-edge. the subjects lined contain the elemental thought, mechanism, varieties of reactions concerned, and the instrumental concepts. The booklet additionally examines the functions of ECL in lots of of the rising fields of technological know-how, resembling bioanalytical, analytical, medical, pharmaceutical, forensic, army, microchip, µTAS, and LED. it is going to be useful to bioanalysts, drug analysts, pharmaceutical researchers and different pros all over the world, in addition to to different readers.

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Extra info for Electrogenerated Chemiluminescence: Protocols and Applications

Example text

S. 1 Nonaqueous Electrochemical Media Modern ECL instruments used for the detection of biorelated species are mostly carried out in aqueous media, while early reports display that historically all ECL studies except for luminol systems were conducted in organic media. In case of biorelated species, the purity of the solvent/supporting electrolyte plays a significant role. Trace amounts of water and oxygen present as an impurity either can disable the generation of both reductive and oxidative ECL precursor species at the electrode or may quench the newly formed excited state species.

Leland JK, Powell MJ (1990) Electrogenerated chemiluminescence: an oxidative-reduction type ECL reaction sequence using Tripropyl Amine. J Electrochem Soc 137(10):3127–3131. 2086171 41. Knight AW, Greenway GM (1996) Relationship between structural attributes and observed electrogenerated chemiluminescence (ECL) activity of tertiary amines as potential analytes for the tris(2,2-bipyridine)ruthenium(II) ECL reaction. A review. Analyst 121(11):101R– 106R 42. Miao W, Bard AJ (2004) Electrogenerated chemiluminescence.

In another strategy, rhodamine B was used as a sensitizer to enhance the weak intrinsic ECL of thiamin in alkaline solution with a very low LOD [25]. The process involves energy transfer between the excited oxidation product of thiamin and rhodamine B.

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