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Advances in Chemical Physics, Volume 158: Physical Chemistry by Mitsuru Nagasawa

By Mitsuru Nagasawa

The Advances in Chemical Physics sequence offers the chemical physics box with a discussion board for severe, authoritative reviews of advances in each region of the self-discipline. This quantity explores subject matters from Thermodynamic homes of Polyelectrolyte strategies to ion-binding of polyelectrolytes. The e-book features:

  • The in basic terms sequence of volumes on hand that provides the innovative of analysis in chemical physics
  • Contributions from specialists during this box of research
  • Representative cross-section of analysis that questions tested pondering on chemical solutions
  • An editorial framework that makes the e-book a superb complement to a complicated graduate category in actual chemistry or chemical physics

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Additional info for Advances in Chemical Physics, Volume 158: Physical Chemistry of Polyelectrolyte Solutions

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Fowler and E. A. Guggenheim, Statistical Thermodynamics, University Press, Cambridge (1939). 3. P. Debye and E. Hückel, Phys. , 24, 185 (1923). 4. P. Debye, Phys. , 25, 97 (1924). 5. N. Bjerrum, D. Kgl. Dan. Vid. Selsk. Math. Fys. , 7, 9 (1926). 6. W. Kern, Angew. , 51, 566 (1938); Z. Phys. , A181, 249 (1938); A184, 197, 302 (1939). 7. S. A. Rice and M. , New York (1953). 8. G. S. Manning, J. Chem. , 51, 924, 3249 (1969); Annu. Rev. Phys. , 117 (1972). 9. F. Oosawa, Polyelectrolytes, Marcel Dekker, New York (1970).

J. Hermans and J. T. G. Overbeek, Rec. Trav. , 67, 761 (1948). M. Szwarc, M. Levy and R. McKovitch, J. Am. Chem. , 78, 2656 (1956). (a) T. Kitano, T. Fujimoto and M. Nagasawa, Macromolecules, 7, 719 (1974); (b) T. Kitano, M. Mitsumura, T. Fujimoto and M. , 8, 382 (1975). T. Kitano, T. Fujimoto and M. Nagasawa, Polym. , 9, 153 (1977). T. Fujimoto and M. Nagasawa, Polym. , 7, 397 (1975). T. Fujimoto, N. Ozaki and M. Nagasawa, J. Polym. Sci. Part A, 3, 2259 (1965). Y. Matsushita, H. Furuhashi, H. Choshi, I.

This is reasonable since water is a poor solvent for hydrocarbon backbones, so the polyelectrolyte molecules may have tight, compact conformations at the limit of Cs = ∞ (see Chapter “Molecular Conformation of Linear Polyelectrolytes”, Section “Unperturbed Dimension”). 02 N in the present case, the polyelectrolyte molecules may have the same types of random-flight coils as the nonionic polymers in organic solvents. B. Theories In a polyelectrolyte solution with a certain amount of a neutral simple salt, it is usually assumed that the electrostatic repulsive force between fixed charges can be regarded as a kind of excluded volume effect, which is presented for nonionic polymers.

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